FORMATION OF DIMETHY LAMINE COMPLEXES OF TRIMETHYLPLATINUM(IV) FROM REACTIONS WITH N,N,N’,N’-TETRAMETHYLDIAMINOMETHANE

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Polyhedron-1995-144-515-1-1 Download

Author(s): Edward W. Abel, Duncan H. Goldsworthy | Peter J. Heard | Kenneth Kite.

Type of publication: Journal paper

Abstract: Abstract-Attempts to prepare complexes of trimethylplatinum(IV) with lY,N,N’,N’-tetramethyldiaminomethane (TMDM) as either a chelating or bridging ligand gave only the complexes of dimethylamine [PtMe,X(HNMe,)], (X = Cl, Br and I ; l-3 and [PtMe3(2,2’- hipyridyl)(HNMe,)]+[BF,]’ (4). ‘H NMR evidence showed that only one of the two possible isomers was formed for l-3.

Published URL: https://www.sciencedirect.com/science/article/pii/027753879400268J?via%3Dihub

Date Published: July 12 1994

Publication title: Polyhedron

Publisher: Pergamon

Place of publication: Exeter (United Kingdom)

Pages: 515-519

Subject(s): Chemistry

DOI: https://doi.org/10.1016/0277-5387(94)00268-J