Complexes of Trimethylplatinum(iv) with Butane-2,3-dioneMonoxime

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J.-Chem.-Soc.-Dalton-Trans.-1995-1233-1237Download

Author(s): Abel Edward. W | Heard Peter. J | Orrell Keith. G | Kite Kenneth | Psaila Alexander. F

Type of publication: Journal paper

Abstract: The dimeric complex of butane-2,3-dione monoxime (Hbdm) with trimethylplatinum(IV), [{PtMe3(bdm)}2]1, and its pyridine (py) and 2,2′-bipyridyl (bipy) adducts [PtMe3(bdm)(py)] and [PtMe3(bdm)(bipy)], show three different configurations for the ionised monoxime ligand. Dimer 1 forms a fluxional solvated monomer in co-ordinating solvents. Its solution-state stereodynamics in CD3OD have been measured by two-dimensional exchange NMR spectroscopy and a ‘windscreen-wiper’ mechanism proposed which is novel in trimethylplatinum(IV) chemistry.

Published URL: https://pubs.rsc.org/en/content/articlelanding/1995/dt/dt9950001233

Date Published: January 1 1995

Publication title: Complexes of Trimethylplatinum(iv) with Butane-2,3-dione Monoxime

Publisher: Dalton Transactions

Pages: 1233-1237

Subject(s): Chemistry

DOI: DOI https://doi.org/10.1039/DT9950001233

Keywords: trimethylplatinum(IV) | butane | monoxime | monomer | fluxional solvated

Depositing User: Victoria Rendell